TITLE: Bio-optical properties of Antarctic coastal waters AUTHORS: Heidi Dierssen, Raymond C. Smith, Karen S. Baker DATE: 9-13 November 1998 PLACE: Kona, Hawaii SPIE14 The International Society for Optical Engineering LTER Contribution #169 Abstract In Antarctic coastal waters, primary production is tightly coupled to chlorophyll concentrations. However, retrieval of chlorophyll concentrations from remotely sensed reflectance measurements using standard algorithms may not be accurate for Southern Ocean waters. The relationship between water-leaving radiance and pigment concentrations has been found to be significantly different in the Southern Ocean compared to other oceanic regions. Here we evaluate a large bio-optical dataset (>1000 samples) collected in Antarctic Peninsula waters in conjunction with the LTER program. The remotely sensed reflectance spectrum appears significantly different for increasing chlorophyll concentrations when compared to the global SeaBAM dataset. The Antarctic reflectance is significantly lower in the green region of the spectrum for high chlorophyll concentrations (>1 mg Chl m-3) and no spectral hinge point is apparent. Because the reflectance in the green is lower, applying the general processing algorithms for both CZCS and SeaWiFS in these Antarctic waters results in underestimates of chlorophyll by roughly a factor of two. Using a radiative transfer model, we show that the shape of the Antarctic remote sensing reflectance spectra is consistent with waters that have very low backscattering, even in high chlorophyll situations. Low coefficients of backscattering could arise because concentrations of bacteria and viruses, the primary backscattering particulates, have been found to be an order of magnitude lower throughout the Southern Ocean when compared to most other oceanic regions.