TITLE: Long-Term Ecological Research (LTER) program: Underway semi-continuous measurements of surface ocean CO2 concentrations AUTHORS: CJ Carrillo and DM Karl DATE: 1997 Palmer LTER Contribution No. xxx Antarctic Journal of the United States, (submitted) Abstract - Accurate estimation of carbon dioxide (CO2) fluxes, coupled with an understanding of the processes that control these fluxes, is necessary to predict future CO2 concentrations in the Southern Ocean. The chemical, physical and biological controls on in situ CO2 concentrations cause habitat variability both temporally and spatially. Open ocean areas presently have high nutrient concentrations but low standing stocks of phytoplankton and low rates of primary production. In sharp contrast to the high nutrient, low productivity open ocean areas, coastal regions of Antarctica exposed to the annual advance and retreat of sea ice, sustain seasonal phytoplankton blooms with high rates of primary production (Smith and Nelson 1985; Holm-Hansen et al. 1989). Consequently, coastal and ice-edge regions of Antarctica could potentially remove atmospheric CO2, but these local sinks may be offset by equally large sources of CO2 during winter periods of net heterotrophy or as a result of the upwelling of CO2-enriched waters. The seasonal advance of the ice in the fall and retreat in the spring may also affect the flux of CO2 in ice-dominated Southern and Arctic Oceans. Quantifying these fluxes will require sampling in the dissimilar ecosystems that make up the Southern Ocean. The Palmer Long-Term Ecological Research (LTER) Program was established in 1990 to study the physical determinants on the Antarctic marine ecosystem. The central tenet of the LTER program is that the annual advance and retreat of sea ice is a major physical determinant of spatial and temporal changes in the structure and function of the Antarctic Marine ecosystem, from total annual primary production to breeding successes in seabirds (Smith et al. 1995).